Uranium(IV) amido-borohydrides as highly active diene polymerisation catalysts.
نویسندگان
چکیده
The synthesis and structural characterisation of the uranium(IV) amido-borohydrides (N'')2U{κ(2)-N(SiMe3)SiMe2CH2BBN-H} and U{κ(2)-N(SiMe3)SiMe2CH2BBN-H}2, and their activity as pre-catalysts for the polymerisation of isoprene are described.
منابع مشابه
Synthesis and structure of divalent thulium borohydrides, and their application in ε-caprolactone polymerisation.
The new divalent thulium compound [Tm(BH(4))(2)(DME)(2)] could be prepared by reduction of [Tm(BH(4))(3)(THF)(3)] or from TmI(2) and KBH(4). It was used as a precursor to the divalent [(Tp(tBu,Me))Tm(BH(4))(THF)] by reaction with potassium tris(2-tBu-4-Me)pyrazolylborate (KTp(tBu,Me)). Both Tm(II) compounds were found active as ε-caprolactone polymerisation catalysts.
متن کاملBis(phenolate)amine-supported lanthanide borohydride complexes for styrene and trans-1,4-isoprene (co-)polymerisations.
New bis(phenolate)amine-supported neodymium borohydride complexes and their previously reported samarium analogues were tested as catalysts for the polymerisation of styrene and isoprene. Reaction of Na2O2N(L) (L = py, OMe, NMe2) with Nd(BH4)3(THF)3 afforded the borohydride complexes Nd(O2N(L))(BH4)(THF) (L = py (1-Nd), OMe (2-Nd), NMe2 (3-Nd)). Complex 1-Nd has shown a propensity to form pheno...
متن کاملRing opening polymerisation of lactide with uranium(iv) and cerium(iv) phosphinoaryloxide complexes.
The C3-symmetric uranium(iv) and cerium(iv) complexes Me3SiOM(OArP)3, M = U (1), Ce (2), OArP = OC6H2-6-tBu-4-Me-2-PPh2, have been prepared and the difference between these 4f and 5f congeners as initiators for the ring opening polymerisation (ROP) of l-lactide is compared. The poorly controlled reactivity of the homoleptic analogue U(OArP)4 (3) demonstrates the importance of the M-OSiMe3 initi...
متن کاملCyclopentadienyl titanium hydroxylaminato complexes as highly active catalysts for the polymerization of propylene.
Half sandwich complexes of titanium bearing eta1 or eta2 bound nitroxide ligands are highly active catalysts for the polymerisation of propylene to high molecular weight atactic poly(propylene).
متن کاملTuning the catalytic properties of rare earth borohydrides for the polymerisation of isoprene.
Previous results obtained for the cis-polymerisation of isoprene with scandium half-sandwich complex Cp*Sc(BH(4))(2)(THF) 1a were extended to its neodymium analog. The X-ray structure of the already reported neodymium monomer compound Cp*Nd(BH(4))(2)(THF)(2) 1b is presented. Cp*Nd(BH(4))(2)(THF)(2)/[CPh(3)][B(C(6)F(5))(4)]/Al((i)Bu)(3) catalytic system was found to be very active and stereosele...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Dalton transactions
دوره 42 25 شماره
صفحات -
تاریخ انتشار 2013